Jm. Liu et al., CRITICAL SPLITTING OF THE SOLIDIFYING INTERFACE GEOMETRICAL MODEL OF SPACING SELECTION DURING DIRECTIONAL SOLIDIFICATION OF LAMELLAR EUTECTICS, Journal of Materials Science, 29(11), 1994, pp. 3085-3094
The steady-state coupling equations of directional solidification of A
l-Al2Cu (epsilon = 0.94), Sn-Pb (epsilon = 0.59) and Al-Si (epsilon =
0.17)eutectics have been solved numerically. The profiles, splitting f
eatures and supercooling of the solidifying interface were investigate
d in detail as functions of the lamellar spacing. It was found that wh
en supercooling, DELTAT0, at the three-phase conjunction point reaches
its minimum value, min (DELTAT0), the solidifying interface prof ile
of one lamellar phase was in the critical splitting state (marginally
stable state) and that of the other lamella was super-stable. Langer's
marginal stability theory of lamellar eutectic solidification with a
planar interface was extended to the case with a curved interface, and
a geometrical model of the spacing selection has been suggested (crit
ical splitting state of one lamella's solidifying interface). The gene
ral scaling law of the spacing, derived according to this theory, was
found to be consistent with the similarity law recently derived by Kas
sner and Misbah; it is also supported by experimental results. Another
geometrical model of the spacing selection was found, where the solid
ifying interface profile of one lamella became split and other lamella
's profile was in the critical splitting state. The experimental data
for directional solidification of Al-Si eutectic showed that the irreg
ular eutectics have a spacing selected according to this mode.