Se. Kesler et al., ROLE OF CRUDE-OIL IN THE GENESIS OF MISSISSIPPI VALLEY-TYPE DEPOSITS - EVIDENCE FROM THE CINCINNATI ARCH, Geology, 22(7), 1994, pp. 609-612
Mississippi Valley-type (MVT sulfide minerals and oil from deposits al
ong the Cincinnati arch have almost identical deltaS-34 values (-9 par
ts per thousand to +9 parts per thousand for MVT sulfides; -12 parts p
er thousand to + 9 parts per thousand for oils). These values are very
similar to those for MVT sulfides and oil in the Illinois-Kentucky di
strict and support their proposed inclusion in a regional hydrothermal
system. Many MVT deposits with low deltaS-34 values are closely assoc
iated with oil, whereas MVT deposits with high deltaS-34 values often
contain bitumen. Reduced sulfur in MVT deposits with high deltaS-34 va
lues probably came from thermochemical sulfate reduction, whereas that
in MVT deposits with low deltaS-34 values probably came from oil and
related organic matter. Oil-related sulfur could have been derived fro
m oil fields or disseminated oil and other organic matter in regional
wallrocks.