POLYCYCLIC OZONIDES AND PEROXIDES DERIVED FROM HEXAMETHYL(DEWAR BENZENE)

Authors
MCCULLOUGH KJ TANAKA S TESHIMA K NOJIMA M
Citation
Kj. Mccullough et al., POLYCYCLIC OZONIDES AND PEROXIDES DERIVED FROM HEXAMETHYL(DEWAR BENZENE), Tetrahedron, 50(25), 1994, pp. 7625-7634
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
25
Year of publication
1994
Pages
7625 - 7634
Database
ISI
SICI code
0040-4020(1994)50:25<7625:POAPDF>2.0.ZU;2-F
Abstract
A stable, crystalline diozonide, derived from Hexamethyl(Dewar Benzene ) 1, has been shown by X-ray crystallographic analysis to be the endo, endoisomer 3c which had been predicted to be less stable than the endo ,exo-isomer 3b. Acidolysis of the trans-ozonide 5 in CF3CO2H/CH2Cl2 ga ve a stable crystalline tricyclic peroxide 6 whereas the isomeric cis- ozonide 7 decomposed under similar conditions.