O. Teschke et al., PHOTOLUMINESCENCE SPECTRUM REDSHIFTING OF POROUS SILICON BY A POLYMERIC CARBON LAYER, Applied physics letters, 64(26), 1994, pp. 3590-3592
Photoluminescence of porous silicon at room temperature shifts to a la
rger wavelength in low-resistivity Si samples (0.006 OMEGA cm) when co
mpared to the one emitted by high resistivity samples (0.4 OMEGA cm).
This shift is associated with a coating of hydrocarbon over the porous
silicon structure. The hydrocarbon coating was identified by electron
energy loss spectroscopy imaging together with infrared spectroscopy.