THE HYDROSILYLATION OF ALDIMINES AND KETIMINES CATALYZED BY TITANOCENE COMPLEXES

Authors
TILLACK A LEFEBER C PEULECKE N THOMAS D ROSENTHAL U
Citation
A. Tillack et al., THE HYDROSILYLATION OF ALDIMINES AND KETIMINES CATALYZED BY TITANOCENE COMPLEXES, Tetrahedron letters, 38(9), 1997, pp. 1533-1534
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
9
Year of publication
1997
Pages
1533 - 1534
Database
ISI
SICI code
0040-4039(1997)38:9<1533:THOAAK>2.0.ZU;2-Q
Abstract
Different titanocene complexes 1 - 10 were tested in the catalytic hyd rosilylation of ald and ketimines with Ph(2)SiH(2). The highest conver sions were obtained with Cp(2)Ti(Ph=CSiMe(3)) 1 up to 98 % at room tem perature. (C) 1997 Elsevier Science Ltd.