ALLENYL(VINYL)METHANE PHOTOCHEMISTRY - PHOTOCHEMISTRY OF 4,4,7-TRIMETHYL-5-PHENYL-2,5,6-OCTATRIENATE DERIVATIVES

Authors
TSUNO T HOSHINO H SUGIYAMA K
Citation
T. Tsuno et al., ALLENYL(VINYL)METHANE PHOTOCHEMISTRY - PHOTOCHEMISTRY OF 4,4,7-TRIMETHYL-5-PHENYL-2,5,6-OCTATRIENATE DERIVATIVES, Tetrahedron letters, 38(9), 1997, pp. 1581-1584
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
9
Year of publication
1997
Pages
1581 - 1584
Database
ISI
SICI code
0040-4039(1997)38:9<1581:AP-PO4>2.0.ZU;2-M
Abstract
The direct photolysis of the diester in the title compounds gave a cro ss conjugated triene, [2+2] cycloadduct, pyran, and cyclopropene. The direct photolysis of the monoester afforded a cross conjugated triene, [2+2] cycloadduct, cyclopropene, and its Z-form. The sensitized photo lysis of these esters afforded the trienes and [2+2] cycloadducts, whi ch were derived from the triplet excited state of the different chromo phores. (C) 1997 Elsevier Science Ltd.