A NEW METHOD FOR THE REGIO AND STEREOSELECTIVE HYDROCARBOXYLATION OF ALKYNES USING NAHFE(CO)(4) CH2CL2 SYSTEM/

Authors
PERIASAMY M RADHAKRISHNAN U RAMESHKUMAR C BRUNET JJ
Citation
M. Periasamy et al., A NEW METHOD FOR THE REGIO AND STEREOSELECTIVE HYDROCARBOXYLATION OF ALKYNES USING NAHFE(CO)(4) CH2CL2 SYSTEM/, Tetrahedron letters, 38(9), 1997, pp. 1623-1626
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
9
Year of publication
1997
Pages
1623 - 1626
Database
ISI
SICI code
0040-4039(1997)38:9<1623:ANMFTR>2.0.ZU;2-D
Abstract
The reagent generated in situ in THF using NaHFe(CO)(4) and CH2Cl2 was used for tile regio and stereoselective hydrocarboxylation of termina l and internal alkynes to obtain alpha,beta-unsaturated carboxylic aci d derivatives. (C) 1997 Published by Elsevier Science Ltd.