The decrease of the electrical conductivity in air of both electrochem
ically and chemically synthesized polypyrroles is studied. This decrea
se is found to be due to oxidative degradation. It appears to follow a
first-order kinetics. The decrease of the conductivity is larger for
the chemically synthesized polypyrrole than for the electrochemically
synthesized one because of the larger surface area of the polymer part
icles in the former.