An exact expression for the mass-gap, the ratio of the physical partic
le mass to the LAMBDA-parameter, is found for the principal chiral sig
ma models associated to all the classical Lie algebras. The calculatio
n is based on a comparison of the free-energy in the presence of a sou
rce coupling to a conserved charge of the theory computed in two ways:
via the Thermodynamic Bethe Ansatz from the exact scattering matrix a
nd directly in perturbation theory. The calculation provides a non-tri
vial test of the form of the exact scattering matrix.