The present paper covers the investigation and application of dual car
bon fiber microelectrodes. The electrodes were characterized by cyclic
voltammetry and chronoamperometry respectively. The steady state curr
ent equation of dual parallel microelectrodes is verified experimental
ly and the deviation between the theoretic curve and the experimental
was discussed. Furthermore, Vitamin B1 was detected indirectly in gene
rator-collector mode at the electrodes. The satisfactory results were
obtained with detection limit of 1.0x 10(-6)mol. dm-3 and the linear c
alibration graph range over 7.5x 10(-4) to 7.5x 10(-6)mol. dm-3 of Vit
amin B1.