CLUSTER QUANTUM-CHEMICAL STUDY OF THE MECHANISM OF SELECTIVE OXIDATION OF ETHANE TO ACETALDEHYDE ON BORON - PHOSPHORUS MIXED-OXIDE CATALYSTS .2. INFLUENCE OF ADDITIVES

Authors
ZHANPEISOV NU OTSUKA K
Citation
Nu. Zhanpeisov et K. Otsuka, CLUSTER QUANTUM-CHEMICAL STUDY OF THE MECHANISM OF SELECTIVE OXIDATION OF ETHANE TO ACETALDEHYDE ON BORON - PHOSPHORUS MIXED-OXIDE CATALYSTS .2. INFLUENCE OF ADDITIVES, Reaction kinetics and catalysis letters, 52(1), 1994, pp. 27-33
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
52
Issue
1
Year of publication
1994
Pages
27 - 33
Database
ISI
SICI code
0133-1736(1994)52:1<27:CQSOTM>2.0.ZU;2-M
Abstract
Selective oxidation of ethane to acetaldehyde on a boron phosphate dop ed by magnesium or zinc oxides was considered using a semiempirical qu antum chemical MINDO/3 method. Catalytic activity of boron phosphate i s shown to enhance when the catalyst contains small amounts of MgO or ZnO. On the basis of calculated results a possible mechanism of this p rocess is proposed.