INCLUSION COMPLEXATION OF SODIUM ALKYL SULFATES WITH BETA-CYCLODEXTRIN - H-1-NMR STUDY

Authors
GUO QX LI ZZ REN T ZHU XQ LIU YC
Citation
Qx. Guo et al., INCLUSION COMPLEXATION OF SODIUM ALKYL SULFATES WITH BETA-CYCLODEXTRIN - H-1-NMR STUDY, Journal of inclusion phenomena and molecular recognition in chemistry, 17(2), 1994, pp. 149-156
Citations number
15
Categorie Soggetti
Chemistry,Crystallography
Journal title
Journal of inclusion phenomena and molecular recognition in chemistry → ACNP
ISSN journal
09230750
Volume
17
Issue
2
Year of publication
1994
Pages
149 - 156
Database
ISI
SICI code
0923-0750(1994)17:2<149:ICOSAS>2.0.ZU;2-#
Abstract
The association of anionic surfactants, viz., sodium alkyl sulfates, C nH2n+1OSO3Na (n = 5, 6, 7, 8, 9, 10, 12), with beta-cyclodextrin has b een investigated by means of NMR spectroscopy. The measurements of che mical shift changes of certain protons of both host and guest molecule s indicated 1 : 1 inclusion complex formation. The association constan ts (K(a)) and standard free energy changes (-DELTAG0) for the inclusio n complexation reaction vary as a function of the hydrocarbon chain le ngth of the surfactants.