TANDEM-BISALKYLATION OF 2-TRIALKYLSILYL-1,3-DITHIANE - A NEW SEQUENTIAL TRANSFORMATION FOR THE SYNTHESIS OF C2-SYMMETRICAL ENANTIOPURE 1,5-DIOLS AND BETA-BETA'-DIHYDROXYKETONES AS WELL AS OF ENANTIOPURE 1,3,5-TRIOLS

Authors
TIETZE LF GEISSLER H GEWERT JA JAKOBI U
Citation
Lf. Tietze et al., TANDEM-BISALKYLATION OF 2-TRIALKYLSILYL-1,3-DITHIANE - A NEW SEQUENTIAL TRANSFORMATION FOR THE SYNTHESIS OF C2-SYMMETRICAL ENANTIOPURE 1,5-DIOLS AND BETA-BETA'-DIHYDROXYKETONES AS WELL AS OF ENANTIOPURE 1,3,5-TRIOLS, Synlett, (7), 1994, pp. 511-512
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1994
Pages
511 - 512
Database
ISI
SICI code
0936-5214(1994):7<511:TO2-AN>2.0.ZU;2-8
Abstract
The synthesis of C2-symmetrical enantiopure 1,5-diols and 3-oxo-1,5-di ols as well as of enantiopure 1,3,5-triols by a new tandem-reaction co nsisting of a bisalkylation of lithiated 2-trialkylsilyl-1,3-dithiane with epoxides in the presence of a crown ether is described.