REGIOSELECTIVE SYNTHESIS OF ALKENYL SULFIDES FROM ALKENYL TRIFLATES USING PALLADIUM(0) AS CATALYST

Authors
MARTINEZ AG BARCINA JO CEREZO AD SUBRAMANIAN LR
Citation
Ag. Martinez et al., REGIOSELECTIVE SYNTHESIS OF ALKENYL SULFIDES FROM ALKENYL TRIFLATES USING PALLADIUM(0) AS CATALYST, Synlett, (7), 1994, pp. 561-562
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1994
Pages
561 - 562
Database
ISI
SICI code
0936-5214(1994):7<561:RSOASF>2.0.ZU;2-8
Abstract
Secondary alkenyl triflates 2, easily obtained from the corresponding ketones 1, react with lithium thiolates in the presence of Pd(PPh3)4 t o form secondary alkenyl sulfides 3 regioselectively (but not fully st ereospecifically) in good to excellent yields.