This article reviews the pioneering investigations of the luminescence
and photoelectric phenomena in type II heterojunctions based on the G
aInAsSb/GaSb system. This system is remarkable because it is possible
to create and study heterojunctions with both staggered and broken-gap
alignment, depending on the alloy composition. Type II heterojunction
s differ from type I in the existence of adjacent dual quantum wells f
or electrons and holes on both sides of the interface. Simultaneous co
nfinement of electrons and holes in these wells causes unique optical
and electrical properties of such heterojunctions and greatly modifies
the characteristics of optoelectronic devices. The review considers t
he photo- and electroluminescence spectra of GaInAsSb/GaSb heterojunct
ions with staggered band alignment. The importance of tunnelling-assis
ted transitions through the interface in the radiative recombination o
f confined carriers is shown. The influence of these transitions on th
e structure and polarization characteristics of the luminescence spect
ra is considered. A new mechanism of photocurrent gain in isotype n-N
heterojunctions due to hole confinement at the type II interface is di
scussed. Unusual asymmetric electrical properties of type II heterojun
ctions with broken-gap band alignment are demonstrated and discussed i
n connection with their energy band diagrams. Novel IR light sources a
nd photodetectors for the 1.6-4.7 mum spectral range based on the GaIn
AsSb/GaSb system are briefly reviewed.