The break-down of metals vapour (Al, Cu) are simulated near the break-
down threshold values of laser radiation. The approximations of collis
ion-radiation model are used, including the detail kinetics of exited
states with radiation and collision transitions, step-by-step ionisati
on process, unexitation and recombination. Energy balance is based on
two-temperature approximation : for electrons and for heavy particles.
It is shown that the particles concentration in exited states and pla
sma species composition differ rather from Saha-Boltzmann's distributi
on. Strong dependence of the break-down threshold intensity on initial
temperature of neutral and charged particles is shown.