ESTIMATED THERMODYNAMIC STABILITY OF INTERMETALLIDES OF ACTINIDES WITH PLATINUM-GROUP METALS

Authors
KALEVICH ES RYABININ MA VASILEV VY
Citation
Es. Kalevich et al., ESTIMATED THERMODYNAMIC STABILITY OF INTERMETALLIDES OF ACTINIDES WITH PLATINUM-GROUP METALS, Radiochemistry, 35(6), 1993, pp. 636-639
Citations number
16
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
35
Issue
6
Year of publication
1993
Pages
636 - 639
Database
ISI
SICI code
1066-3622(1993)35:6<636:ETSOIO>2.0.ZU;2-9
Abstract
The upper limits of the molar free energy of formation of intermetalli des of actinides (An = Am, Cm, Bk, Cf) with platinum-group metals (M = Pt, Ir, Pd, Rh) AnM(y) (y = 2, 3, 5) are calculated. The quantity DEL TAG0f varies from -340 kJ/mole for Cf compounds to -400 kJ/mole for Am compounds. The change of DELTAG0f(AnMy) as a function of An atomic nu mber correlates with the change of other properties of the studied int ermetallides.