The structure of the polysaccharide from Cercidium praecox (Rand P) Ha
rms gum exudate has been studied by Smith degradation, by sugar and me
thylation analyses, and by C-13 NMR spectroscopy. The results showed a
(1 --> 4)-xylan core. Some xylose residues are substituted at O-2 by
alpha-D-glucuronic acid and 4-O-methyl-alpha-D-glucuronic acid residue
s. beta-D-Glucuronic acid is present, probably as terminal residues. T
he arabinose is present as alpha-L-furanose and beta-L-pyranose.