SILICON-CARBON UNSATURATED-COMPOUNDS .48. SYNTHESIS AND REACTIONS OF SILICON ANALOGS OF LITHIUM ENOLATES

Authors
OHSHITA J MASAOKA Y MASAOKA S ISHIKAWA M TACHIBANA A YANO T YAMABE T
Citation
J. Ohshita et al., SILICON-CARBON UNSATURATED-COMPOUNDS .48. SYNTHESIS AND REACTIONS OF SILICON ANALOGS OF LITHIUM ENOLATES, Journal of organometallic chemistry, 473(1-2), 1994, pp. 15-17
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
473
Issue
1-2
Year of publication
1994
Pages
15 - 17
Database
ISI
SICI code
0022-328X(1994)473:1-2<15:SU.SAR>2.0.ZU;2-7
Abstract
The reaction of mesitoyl- and (2-methylbenzoyl)tris(trimethylsilyl)sil ane with 1 equiv. of a silyllithium gave silicon analogs of lithium en olates. Hydrolysis of the lithium silenolates afforded hydrosilanes in high yields. The lithium silenolates can be readily transformed into silenes quantitatively, by treatment with a chlorosilane.