HYDROTHERMAL SYNTHESIS OF A MIXED-CLUSTER MOLYBDENUM POLYSULFIDE - CS4[MO3S(S2)6][MO3S(S2)5(S4)].0.5H2O

Authors
RAYMOND CC DORHOUT PK MILLER SM
Citation
Cc. Raymond et al., HYDROTHERMAL SYNTHESIS OF A MIXED-CLUSTER MOLYBDENUM POLYSULFIDE - CS4[MO3S(S2)6][MO3S(S2)5(S4)].0.5H2O, Inorganic chemistry, 33(13), 1994, pp. 2703-2704
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
13
Year of publication
1994
Pages
2703 - 2704
Database
ISI
SICI code
0020-1669(1994)33:13<2703:HSOAMM>2.0.ZU;2-S
Abstract
A new mixed-cluster molybdenum sulfide Cs4[Mo3S(S2)6][Mo3S(S2)5(S4)]-0 .5H2O was synthesized by the hydrothermal method and characterized by single-crystal X-ray diffraction. The compound consists of distinct la yers of two types of molybdenum sulfide clusters: type A, [Mo3(mu3-S)( S2)6]2-; type B, [Mo3(mu3-S)(S2)5(S4)]2-. The type B clusters are link ed in one-dimensional chains through weak S-S intercluster interaction s.