The anodic oxidation of silicon in a 0.04 N solution of potassium nitr
ate in ethylene glycol with small amounts of water is a hole consuming
process. Therefore, n-type silicon, anodically biased, behaves in the
dark in many respects as a reverse biased diode. Under steady-state c
onditions a certain, in general a very low electrochemical reaction ra
te is established. If the sample is locally implanted with ions or loc
ally illuminated the ion implanted or illuminated regions can serve as
an additional source of minority carriers and show a faster oxidation
rate than the nonimplanted or nonilluminated areas. The influence of
radiation damage as well as of a focused laser beam (radius 4 mum) on
the local oxidation of anodically biased n-type silicon is discussed.
The electrophysical properties of the silicon/anodic oxide interface a
re investigated by forming Metal/Oxide/Semiconductor (MOS) structures.