NITRAMINOMETHYLATION OF SILYLATED POLYNITROGEN HETEROCYCLIC-COMPOUNDSIN NONAQUEOUS SOLUTIONS

Authors
APASOV ET KALININ AV IOFFE SL TARTAKOVSKY VA
Citation
Et. Apasov et al., NITRAMINOMETHYLATION OF SILYLATED POLYNITROGEN HETEROCYCLIC-COMPOUNDSIN NONAQUEOUS SOLUTIONS, Russian chemical bulletin, 42(9), 1993, pp. 1604-1605
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
9
Year of publication
1993
Pages
1604 - 1605
Database
ISI
SICI code
1066-5285(1993)42:9<1604:NOSPH>2.0.ZU;2-9
Abstract
Trimethylsilyloxy derivatives of 1,2,4-triazole, 3(5)-nitro-1,2,4-tria zole, and tetrazole are inert toward 2-nitro-1-trimethylsilyloxy-2-aza propane, but they react with 1-chloro-2-nitro-2-azapropane to give the corresponding nitraminomethyl derivatives. Silylated 1,2,4-triazole u ndergoes bis-nitraminomethylation to give a triazolium salt.