THERMOCHEMICAL ASPECTS ON THE HYDROLYSIS OF HALOGENOALKYL TITANATES

Authors
BELDIE C ONU A AELENEI N NEMTOI G POPA O
Citation
C. Beldie et al., THERMOCHEMICAL ASPECTS ON THE HYDROLYSIS OF HALOGENOALKYL TITANATES, Revue Roumaine de Chimie, 39(1), 1994, pp. 23-29
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
39
Issue
1
Year of publication
1994
Pages
23 - 29
Database
ISI
SICI code
0035-3930(1994)39:1<23:TAOTHO>2.0.ZU;2-5
Abstract
The caloric effects for hydrolytic reaction of TiCl4 tetrabutoxytitana te and butoxytitanate chlorides were determined using adiabatic calori meter with isothermal mantle. The caloric effect is marcantly dependen t on the water/titanate molar ratio, a maximal value being attained to r 30:1 ratio. In the case of the butoxytitanium chlorides the caloric effect cannot be evaluated by additivity, on the basis of group contri butions.