CALCULATION OF DOUBLY-EXCITED STATES OF HELIUM WITH A FINITE DISCRETESPECTRUM

Authors
Citation
E. Lindroth, CALCULATION OF DOUBLY-EXCITED STATES OF HELIUM WITH A FINITE DISCRETESPECTRUM, Physical review. A, 49(6), 1994, pp. 4473-4480
Citations number
59
Categorie Soggetti
Physics
Journal title
ISSN journal
10502947
Volume
49
Issue
6
Year of publication
1994
Pages
4473 - 4480
Database
ISI
SICI code
1050-2947(1994)49:6<4473:CODSOH>2.0.ZU;2-A
Abstract
Doubly excited states in helium are calculated with many-body perturba tion theory to all orders in the electron-electron interaction. A fini te and numerical basis set, rotated out into the complex plane, is use d. Results, for energies and widths, are presented for states with ele ctrons in the n = 2 and n = 3 states. The possibility of an accuracy o f a few parts in 10(6) is demonstrated. The method is equally applicab le to the study of doubly excited states of many-electron systems and the extension to the corresponding relativistic procedure is straightf orward.