In this work, the redox processes of copper ions were studied bv elect
rochemical methods in NaCl and NaClO4 solutions in the absence or in t
he presence of nonionic surfactant Triton X-100 (T-X-100). The enhance
ment of the anodic peak current of copper in the presence of T-X-100 i
n sodium chloride solutions was observed depending on the concentratio
ns of T-X-100 and copper (11) ions. This is the consequence of destabi
lization of the otherwise stabile CuCl2- complex in chloride solutions
bv the presence of T-X-100. The process involves disproportionation o
f formed copper (I) species to copper (0) and copper (II).