Ho. Georgii, LARGE DEVIATIONS AND THE EQUIVALENCE OF ENSEMBLES FOR GIBBSIAN PARTICLE-SYSTEMS WITH SUPERSTABLE INTERACTION, Probability theory and related fields, 99(2), 1994, pp. 171-195
For Gibbsian systems of particles in R(d), we investigate large deviat
ions of the translation invariant empirical fields in increasing boxes
. The particle interaction is given by a superstable, regular pair pot
ential. The large deviation principle is established for systems with
free or periodic boundary conditions and, under a stronger stability h
ypothesis on the potential, for systems with tempered boundary conditi
ons, and for tempered (infinite-volume) Gibbs measures. As a by-produc
t we obtain the Gibbs variational formula for the pressure. We also pr
ove the asymptotic equivalence of microcanonical and grand canonical G
ibbs distributions and establish a variational expression for the ther
modynamic entropy density.