NONPHOTOCHEMICAL SYNTHESIS AND STRUCTURE OF THE 1ST DONOR-STABILIZED [BIS(SILYLENE)]RUTHENIUM COMPLEX

Authors
TOBITA H WADA H UENO K OGINO H
Citation
H. Tobita et al., NONPHOTOCHEMICAL SYNTHESIS AND STRUCTURE OF THE 1ST DONOR-STABILIZED [BIS(SILYLENE)]RUTHENIUM COMPLEX, Organometallics, 13(7), 1994, pp. 2545-2547
Citations number
51
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
7
Year of publication
1994
Pages
2545 - 2547
Database
ISI
SICI code
0276-7333(1994)13:7<2545:NSASOT>2.0.ZU;2-#
Abstract
The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph3P)Ru (SiMe2---O(Me)---SiMe2), has been synthesized by the thermal reaction of CpRu(Pph3)2Me with HMe2SiSiMe2OMe. The X-ray crystal structure anal ysis of this complex revealed its distorted-piano-stool structure, con taining a RuSi2O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.