REACTIVITY OF A 4-MEMBERED VANADACYCLE RING SUPPORTED BY BULKY SILAZANATE - REGIOSELECTIVE HYDROGENATION OF PYRIDINE

Authors
BERNO P GAMBAROTTA S
Citation
P. Berno et S. Gambarotta, REACTIVITY OF A 4-MEMBERED VANADACYCLE RING SUPPORTED BY BULKY SILAZANATE - REGIOSELECTIVE HYDROGENATION OF PYRIDINE, Organometallics, 13(7), 1994, pp. 2569-2571
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
7
Year of publication
1994
Pages
2569 - 2571
Database
ISI
SICI code
0276-7333(1994)13:7<2569:ROA4VR>2.0.ZU;2-V
Abstract
The dinuclear {[(Me3Si)2N]V[mu-N(SiMe3)-Si(Me2CH2]}2 complex, containi ng a four-membered metallacyclic ring, has been obtained via reaction of VCl3(THF)3 with (Me3Si)2NLi. The reactivity of the metallacycle has been investigated with respect to the coordination of bases, hydrogen ation, and insertion of alkynes.