G. Moumouzias et G. Ritzoulis, CONDUCTOMETRIC STUDY OF BU(4)NCLO(4) IN PROPYLENE CARBONATE-ACETONITRILE AND PROPYLENE CARBONATE-TOLUENE MIXTURES AT 25-DEGREES-C, Journal of solution chemistry, 25(12), 1996, pp. 1271-1280
Conductometric measurements of tetrabutylammonium perchlorate in propy
lene carbonate-acetonitrile and propylene carbonate-toluene mixtures a
t 25 degrees C are reported. Limiting molar conductances, association
constants and distance of closest approach of ions are calculated. The
experimental data were analyzed by means of the Lee-Wheaten equation.
The Gillrerson's solvent-solute interaction energy term was calculate
d from a plot of association constant logarithm vs. reciprocal dielect
ric constant.