Transient capacitance methods were used to analyze traps occurring in
unintentionally doped n-type GaN grown by hydride vapor-phase epitaxy.
Studies by deep-level transient spectroscopy (DLTS) and isothermal ca
pacitance transient spectroscopy indicated the presence of three major
ity-carrier traps occurring at discrete energies below the conduction
band with activation energies (eV) DELTAE1=0.264+/-0.01, DELTAE2=0.580
+/-0.017, and DELTAE3=0.665+/-0.017. The single-crystal films of GaN w
ere grown on GaN formed by metal-organic chemical-vapor deposition and
on sputter-deposited ZnO; a similar deep-level structure was found in
both types of samples. Pulse-width modulation tests using DLTS to det
ermine the capture rates of the traps showed that the capture process
is nonexponential, perhaps due to the high trap concentration. The ori
gins of the deep levels are discussed in light of secondary-ion-mass-s
pectroscopy analysis and group theory results in the literature.