TRIS(1,10-PHENANTHROLINE)IRON(II) DIPERCHLORATE HEMIHYDRATE

Authors
KOH LL XU Y HSIEH AK SONG B WU FH JI LN
Citation
Ll. Koh et al., TRIS(1,10-PHENANTHROLINE)IRON(II) DIPERCHLORATE HEMIHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 884-886
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
6
Pages
884 - 886
Database
ISI
SICI code
0108-2701(1994)50:<884:TDH>2.0.ZU;2-K
Abstract
Crystals of [Fe(phen)3](ClO4)2.0-5H2O (phen = 1,10-phenanthroline) are nearly isostructural with those of the Co(II) and Cu(II) analogues, w ith similar disorder of the perchlorate groups. The Fe(II) complex ion is less distorted than the Co(II) and Cu(II) complex ions. The averag e Fe-N distance is 1.978 (3) angstrom and the average N-Fe-N bidentate angle is 82.6 (4)-degrees. The phenanthroline ligands are planar.