)NEODYMIUM-MU-CHLORO-TRIS(TETRAHYDROFURAN)LITHIUM, [ND(ETA(5)-(T)BUCP)3(MU-CL)LI(THF)3]

Authors
GUAN JW SHEN Q JIN SC LIN YH
Citation
Jw. Guan et al., )NEODYMIUM-MU-CHLORO-TRIS(TETRAHYDROFURAN)LITHIUM, [ND(ETA(5)-(T)BUCP)3(MU-CL)LI(THF)3], Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 891-893
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
6
Pages
891 - 893
Database
ISI
SICI code
0108-2701(1994)50:<891:)[>2.0.ZU;2-L
Abstract
The title complex, 2Cl-tris(tetrahydrofuran-1kappaO)lithiumneodymium, [Nd(C9H13)3(mu-Cl)Li(C4H8O)3], consists of the neutral moiety ((t)BuCp )3Nd linked to the cation [Li(thf)3]+ by a mu-Cl bridge. The Nd atom i s coordinated by three eta5-bonded tert-butylcyclopentadienyl ((t)BuCp ) ligands and a Cl- ion to form a slightly deformed tetrahedron. Nd-Cl = 2.797 (2), Li-Cl = 2.345 (9) angstrom and Nd-Cl-Li = 141.4 (3)-degr ees.