P-METHYL-N-(PENTAFLUOROBENZYLIDENE)ANILINE (1),1,2,3,4-TETRAFLUORO-7-METHOXYACRIDINE (2),1,2,3,4,7-PENTAFLUOROACRIDINE (3) AND (P-METHYLANILINO)-1,2,4-TRIFLUORO-7-METHYLACRIDINE (4) - 4 MOLECULES REPRESENTING KEY STAGES IN THE ONE-POT SYNTHESIS OF 1,2,3,4-TETRAFLUOROACRIDINES BYTREATING PENTAFLUOROBENZALDEHYDE WITH PARASUBSTITUTED ANILINES
Aj. Adamson et al., P-METHYL-N-(PENTAFLUOROBENZYLIDENE)ANILINE (1),1,2,3,4-TETRAFLUORO-7-METHOXYACRIDINE (2),1,2,3,4,7-PENTAFLUOROACRIDINE (3) AND (P-METHYLANILINO)-1,2,4-TRIFLUORO-7-METHYLACRIDINE (4) - 4 MOLECULES REPRESENTING KEY STAGES IN THE ONE-POT SYNTHESIS OF 1,2,3,4-TETRAFLUOROACRIDINES BYTREATING PENTAFLUOROBENZALDEHYDE WITH PARASUBSTITUTED ANILINES, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 967-971
All of the title compounds, C14H8F5N, C14H7F4NO, C13H4F5N and C21H15F3
N2, display a Characteristic stacking of their pi systems in which adj
acent members of the stack are related by crystallographic inversion c
entres. This leads to a particularly efficient mode of packing in whic
h fluorinated rings overlap unfluorinated sections of the molecules at
interplanar spacings ranging from 3.40 to 3.51 angstrom.