NEW MONOSPIROCYCLOTRIPHOSPHAZENES AND TRISPIROCYCLOTRIPHOSPHAZENES FROM THE REACTIONS OF (NPCL2)3 WITH AROMATIC ORTHO DINUCLEOPHILES

Authors
ALLCOCK HR DIEFENBACH U PUCHER SR
Citation
Hr. Allcock et al., NEW MONOSPIROCYCLOTRIPHOSPHAZENES AND TRISPIROCYCLOTRIPHOSPHAZENES FROM THE REACTIONS OF (NPCL2)3 WITH AROMATIC ORTHO DINUCLEOPHILES, Inorganic chemistry, 33(14), 1994, pp. 3091-3095
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
14
Year of publication
1994
Pages
3091 - 3095
Database
ISI
SICI code
0020-1669(1994)33:14<3091:NMATF>2.0.ZU;2-T
Abstract
Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino- 4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dich lorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-dia minopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, a nd 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structure s were examined by IR, P-31 NMR, and H-1 NMR spectroscopy, mass spectr ometry, and elemental analysis.