BINUCLEAR COMPLEXES FROM 1,8-SUBSTITUTED ANTHRACENE-DERIVATIVES - THECRYSTAL-STRUCTURE OF ZONE)](TETRA-CHLOROBIS(ETA-2-ETHYLENE)DI-PLATINUM]

Authors
DEFELICE V RUFFO F TUZI A
Citation
V. Defelice et al., BINUCLEAR COMPLEXES FROM 1,8-SUBSTITUTED ANTHRACENE-DERIVATIVES - THECRYSTAL-STRUCTURE OF ZONE)](TETRA-CHLOROBIS(ETA-2-ETHYLENE)DI-PLATINUM], Inorganica Chimica Acta, 221(1-2), 1994, pp. 151-155
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
221
Issue
1-2
Year of publication
1994
Pages
151 - 155
Database
ISI
SICI code
0020-1693(1994)221:1-2<151:BCF1A->2.0.ZU;2-V
Abstract
Oxidative addition of anthracene 1,8-dicarbonylchloride to the three-c oordinate Pt(2,9-Me2-1,10-phenanthroline)(dimethylmaleate)], leads to a binuclear species with trigonal bipyramidal coordination around each platinum atom. Some reactions of this complex are described. The crys tal structure of the related ethylene four-coordinate species azone)]} tetrachlorobis(eta2-ethylene)di-platinum], is reported. The complex cr ystallizes in the triclinic space group P1BAR with: a = 7.185(3), b = 13.379(7), c = 14.943(7) angstrom, alpha = 103.49(4), beta = 93.48(4), gamma = 97.78(4)degrees, Z = 2, R = 0.065.