Hs. Park et al., THE REACTION OF CPRU(PPH3)2- SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF [CPRU(PPH3)2(SC3H6)]CF3SO3( WITH TRIMETHYLENESULFIDE ), Inorganica Chimica Acta, 221(1-2), 1994, pp. 157-160
The isolation and characterization of the trimethylenesulfide-coordina
ted complex, [CpRu(PPh3)2(SC3H6)]CF3SO3, is reported. The structure of
[CpRu(PPh3)2(SC3H6)]CF3SO3 was determined by X-ray diffraction techni
ques: monoclinic space group I2/a, a = 23.864(10), b = 14.233(3), c =
24.385(7) angstrom, beta = 97.10(3)degrees, Z = 8, R = 0.046, R(w) = 0
.065. The Ru is attached to two triphenylphosphine ligands, a cyclopen
tadienyl and the trimethylenesulfide. The Ru-S distance is 2.3459(20)
angstrom.