THE REACTION OF CPRU(PPH3)2- SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF [CPRU(PPH3)2(SC3H6)]CF3SO3( WITH TRIMETHYLENESULFIDE )

Authors
PARK HS DRAGANJAC M SCOTT SR CORDES AW EGGLETON G
Citation
Hs. Park et al., THE REACTION OF CPRU(PPH3)2- SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF [CPRU(PPH3)2(SC3H6)]CF3SO3( WITH TRIMETHYLENESULFIDE ), Inorganica Chimica Acta, 221(1-2), 1994, pp. 157-160
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
221
Issue
1-2
Year of publication
1994
Pages
157 - 160
Database
ISI
SICI code
0020-1693(1994)221:1-2<157:TROCSA>2.0.ZU;2-H
Abstract
The isolation and characterization of the trimethylenesulfide-coordina ted complex, [CpRu(PPh3)2(SC3H6)]CF3SO3, is reported. The structure of [CpRu(PPh3)2(SC3H6)]CF3SO3 was determined by X-ray diffraction techni ques: monoclinic space group I2/a, a = 23.864(10), b = 14.233(3), c = 24.385(7) angstrom, beta = 97.10(3)degrees, Z = 8, R = 0.046, R(w) = 0 .065. The Ru is attached to two triphenylphosphine ligands, a cyclopen tadienyl and the trimethylenesulfide. The Ru-S distance is 2.3459(20) angstrom.