K. Kimura et al., A FATAL DISASTER CASE-BASED ON EXPOSURE TO HYDROGEN-SULFIDE - AN ESTIMATION OF THE HYDROGEN-SULFIDE CONCENTRATION AT THE SCENE, Forensic science international, 66(2), 1994, pp. 111-116
Four adult men fell into an artificial lake which was being used to ra
ise flatfish, after a water pipe had been connected to a tube allowing
seawater to flow into the lake. Forensic autopsies were carried out o
n three of the four men, who died soon after the incident. From autops
y findings, the cause of death was diagnosed to be suffocation after a
spirating seawater in the three victims. To clarify why the men fell i
nto the lake, a chemical analysis for hydrogen sulfide was carried out
using the extractive alkylation technique combined with gas chromatog
raphy/mass spectrometry. The sulfide was detected as its derivative, b
is(pentafluorobenzyl)sulfide, in body tissues taken from all the victi
ms, and the concentration of hydrogen sulfide gas at the scene was est
imated as having been nearly fatal.