FLUORIDE-ION CATALYSIS IN THE HYDROLYSIS OF ARYL PHOSPHATES - DEACTIVATING EFFECT OF LITHIUM COUNTER ION

Authors
MENTZ M MODRO AM MODRO TA
Citation
M. Mentz et al., FLUORIDE-ION CATALYSIS IN THE HYDROLYSIS OF ARYL PHOSPHATES - DEACTIVATING EFFECT OF LITHIUM COUNTER ION, Journal of the Chemical Society, Chemical Communications, (13), 1994, pp. 1537-1538
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1994
Pages
1537 - 1538
Database
ISI
SICI code
0022-4936(1994):13<1537:FCITHO>2.0.ZU;2-O
Abstract
Hydrolysis of the P-OAr bond in dimethyl aryl phosphates is catalysed by fluoride ion due to the fast formation of intermediate phosphoroflu oridate; LiF shows a much weaker catalytic effect than other alkali me tal and tetramethylammonium fluoride salts.