A DIMETHYLDIOXIRANE-MEDIATED ROUTE TO ENANTIOMERICALLY PURE TRICARBONYLCHROMIUM(0) COMPLEXES OF ORTHO-SUBSTITUTED STYRENES

Authors
CHRISTIAN PWN GIL R MUNIZFERNANDEZ K THOMAS SE WIERZCHLEYSKI AT
Citation
Pwn. Christian et al., A DIMETHYLDIOXIRANE-MEDIATED ROUTE TO ENANTIOMERICALLY PURE TRICARBONYLCHROMIUM(0) COMPLEXES OF ORTHO-SUBSTITUTED STYRENES, Journal of the Chemical Society, Chemical Communications, (13), 1994, pp. 1569-1570
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1994
Pages
1569 - 1570
Database
ISI
SICI code
0022-4936(1994):13<1569:ADRTEP>2.0.ZU;2-6
Abstract
Dimethyldioxirane oxidation of tricarbonylchromium(0) complexes of a r ange of ortho-substituted (S)-alpha-methylbenzyldimethylamines 3a-f pr oceeds smoothly to give enantiomerically pure tricarbonylchromium(0) c omplexes of ortho-substituted styrenes 4a-f via chemoselective oxidati on of the tertiary amines to their N-oxides and subsequent Cope reacti ons.