COMPLETELY STEREOSELECTIVE SYNTHESIS OF A CHIRAL QUADRIDENTATE LIGANDWITH AS2NP DONOR ATOMS - CRYSTAL AND MOLECULAR-STRUCTURE OF [OC-6,35-(R-ASTERISK,S-ASTERISK)]-(+ NYL)METHYLPHOSPHINO]BENZENE-AS,AS',N,P)COBALT(III) CHLORIDE DIHYDRATE/

Authors
DOYLE RJ SALEM G WILLIS AC
Citation
Rj. Doyle et al., COMPLETELY STEREOSELECTIVE SYNTHESIS OF A CHIRAL QUADRIDENTATE LIGANDWITH AS2NP DONOR ATOMS - CRYSTAL AND MOLECULAR-STRUCTURE OF [OC-6,35-(R-ASTERISK,S-ASTERISK)]-(+ NYL)METHYLPHOSPHINO]BENZENE-AS,AS',N,P)COBALT(III) CHLORIDE DIHYDRATE/, Journal of the Chemical Society, Chemical Communications, (13), 1994, pp. 1587-1588
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1994
Pages
1587 - 1588
Database
ISI
SICI code
0022-4936(1994):13<1587:CSSOAC>2.0.ZU;2-C
Abstract
Reaction of /-)-(2-aminophenyl)(2-chlorophenyl)methylphosphine with so dium (2-dimethylarsinophenyl)methylarsenide is completely stereoselect ive giving [(2-aminophenyl)methylphosphino]benzene,(R,S*)-1; as confi rmed by a crystal structure determination of cis-[CoCl2{(R,S*)-1}]Cl. 2H(2)O.