NOVEL PHOSPHONIUM-BETAINE LIGANDS [SC(H)PPH(3)-C,S]- AND [S(H)C=C(PPH(3))S-S,S']- STABILIZED IN RHODACARBORANE COMPLEXES

Authors
FERGUSON G GALLAGHER JF JENNINGS MC COUGHLAN S SPALDING TR KENNEDY JD FONTAINE XLR
Citation
G. Ferguson et al., NOVEL PHOSPHONIUM-BETAINE LIGANDS [SC(H)PPH(3)-C,S]- AND [S(H)C=C(PPH(3))S-S,S']- STABILIZED IN RHODACARBORANE COMPLEXES, Journal of the Chemical Society, Chemical Communications, (13), 1994, pp. 1595-1596
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1994
Pages
1595 - 1596
Database
ISI
SICI code
0022-4936(1994):13<1595:NPL[A[>2.0.ZU;2-D
Abstract
Two novel phosphonium-betaine ligands [SC(H)PPh(3)](-) and [S(H)C=C(PP h(3))S](-) are stabilised in the twelve-vertex close-type rhodacarbora ne complexes 3-{eta(2)-SC(H)PPh(3)}-3-(PPh(3))-3,1,2-RhC2B9H11] and [2 -{eta(2)-S(H)C=C(PPh(3))S}-2,1,7-RhC2B9H11] which are characterised sp ectroscopically and by X-ray diffraction methods.