NEW MACROMOLECULAR HOST SYSTEMS - PREPARATION AND STRUCTURE OF CERTAIN FUNCTIONALIZED 2,6-DIARYL-CIS-1,3,5,7-TETRAOXADECALIN PODAND COMPOUNDS AND MACRO-M-CYCLOPHANES
S. Abramson et al., NEW MACROMOLECULAR HOST SYSTEMS - PREPARATION AND STRUCTURE OF CERTAIN FUNCTIONALIZED 2,6-DIARYL-CIS-1,3,5,7-TETRAOXADECALIN PODAND COMPOUNDS AND MACRO-M-CYCLOPHANES, Journal of the Chemical Society, Chemical Communications, (13), 1994, pp. 1611-1612
A series of new podands consisting of 2,6-cis-diaryl-1,3,5,7-tetraoxad
ecalin systems 2-7 have been prepared and fully characterized; the cry
stal structure of (2R,6R,9S; -cis-2,6-di(p-nitrophenyl)-1,3,5,7-tetrao
xadecalin 4 showed characteristic 'host-guest' packing and structural
data which fitted well with the stereoelectronic features of the cis-1
,3,5,7-tod system and a new class of macro-cyclophanes (9, 10) was unr
avelled.