J. Vindevogel et P. Sandra, ON THE POSSIBILITY OF PERFORMING CHIRAL WALL-COATED OPEN-TUBULAR ELECTROCHROMATOGRAPHY IN 50-MU-M INTERNAL DIAMETER CAPILLARIES, Electrophoresis, 15(6), 1994, pp. 842-847
Recent results have demonstrated acceptable enantiomer separations in
open, 50 mu m internal diameter capillaries, coated with a chiral stat
ionary phase, a technique known as electrochromatography. According to
existing literature, smaller column diameters, 10 mu m or less, are g
enerally preferred for this mode of operation. The conditions under wh
ich the wider columns can be used are discussed.