RADICAL CATIONS OF 1,2-BIS(DIALKYLAMINO)BENZENES - RESTRICTED ROTATION ABOUT THE C-NME(2) BOND

Authors
NEUGEBAUER FA FUNK B STAAB HA
Citation
Fa. Neugebauer et al., RADICAL CATIONS OF 1,2-BIS(DIALKYLAMINO)BENZENES - RESTRICTED ROTATION ABOUT THE C-NME(2) BOND, Tetrahedron letters, 35(27), 1994, pp. 4755-4758
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
27
Year of publication
1994
Pages
4755 - 4758
Database
ISI
SICI code
0040-4039(1994)35:27<4755:RCO1-R>2.0.ZU;2-U
Abstract
The 1,2-bis(dialkylamino)benzene radical cations 2a-c(.+) were generat ed by oxidation of the parent compounds with iodine or lead tetraaceta te. ESR and ENDOR studies of 2a(.+) and 2b(.+) gave evidence of a rest ricted rotation about the C-NMe(2) bond; based on the results of 2c(.) the different N-methyl proton splittings in 2a(.+) and 2b(.+) were a ssigned to the exo and endo N-methyl groups.