A BETA,BETA,BETA-TRIALKOXYETHYLLITHIUM STABLE TOWARDS FRAGMENTATION -A CARBOXYL PROTECTED ACETIC-ACID DIANION EQUIVALENT

Authors
CHANDRASEKHAR S ROY CD
Citation
S. Chandrasekhar et Cd. Roy, A BETA,BETA,BETA-TRIALKOXYETHYLLITHIUM STABLE TOWARDS FRAGMENTATION -A CARBOXYL PROTECTED ACETIC-ACID DIANION EQUIVALENT, Tetrahedron, 50(27), 1994, pp. 8099-8102
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
27
Year of publication
1994
Pages
8099 - 8102
Database
ISI
SICI code
0040-4020(1994)50:27<8099:ABSTF->2.0.ZU;2-K
Abstract
The novel alkyllithium 1b is not only intriguingly stable towards frag mentation, but also a synthetically useful reagent, complementing curr ent carboxylic ester enolate methodology. Its design is based on inter esting mechanistic principles, and harnesses the known stability of th e 2,4,10-trioxaadamantane framework.