PHOTOINDUCED ELECTRON-TRANSFER (PET) PROMOTED CYCLIZATIONS OF 1-[N-ALKYL-N-(TRIMETHYLSILYL)METHYL]AMINES TETHERED TO PROXIMATE OLEFIN - MECHANISTIC AND SYNTHETIC PERSPECTIVES

Authors
PANDEY G REDDY GD KUMARASWAMY G
Citation
G. Pandey et al., PHOTOINDUCED ELECTRON-TRANSFER (PET) PROMOTED CYCLIZATIONS OF 1-[N-ALKYL-N-(TRIMETHYLSILYL)METHYL]AMINES TETHERED TO PROXIMATE OLEFIN - MECHANISTIC AND SYNTHETIC PERSPECTIVES, Tetrahedron, 50(27), 1994, pp. 8185-8194
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
27
Year of publication
1994
Pages
8185 - 8194
Database
ISI
SICI code
0040-4020(1994)50:27<8185:PE(PCO>2.0.ZU;2-8
Abstract
Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised alpha-silylmethyl amine radical cation as reactive interme diate in such cyclisations are described.