REACTION OF 2,4-DICHLOROPHENYLGLYOXYLHYDROXIMOYL CHLORIDE WITH AMINESAS A CONVENIENT METHOD FOR THE SYNTHESIS OF AMIDE OXIMES AND AMIDES

Authors
JAROSKOVA L FISERA L
Citation
L. Jaroskova et L. Fisera, REACTION OF 2,4-DICHLOROPHENYLGLYOXYLHYDROXIMOYL CHLORIDE WITH AMINESAS A CONVENIENT METHOD FOR THE SYNTHESIS OF AMIDE OXIMES AND AMIDES, Chemicke zvesti, 48(1), 1994, pp. 31-34
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemicke zvesti → ACNP
ISSN journal
03666352
Volume
48
Issue
1
Year of publication
1994
Pages
31 - 34
Database
ISI
SICI code
0366-6352(1994)48:1<31:RO2CWA>2.0.ZU;2-N
Abstract
2,4-Dichlorobenzoylnitrile oxide (I) generated in situ from the title compound reacts with amines under the condition of 1,3-dipolar cycload dition to afford the amide oximes IV and amides V. The ratio of IV and V depends on the structure of amine. Reaction of I with cyclic amines gave only IV. The reaction mechanism is briefly discussed.