SYNTHESIS AND STRUCTURE OF GOLD(III), PALLADIUM(II) AND PLATINUM(IV) COMPLEXES WITH THE SCHIFF-BASE OF PICOLINALDEHYDE N-OXIDE AND SEMICARBAZIDE

Authors
GONG YQ CHEN CG HUAN XF
Citation
Yq. Gong et al., SYNTHESIS AND STRUCTURE OF GOLD(III), PALLADIUM(II) AND PLATINUM(IV) COMPLEXES WITH THE SCHIFF-BASE OF PICOLINALDEHYDE N-OXIDE AND SEMICARBAZIDE, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(6), 1994, pp. 877-889
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
24
Issue
6
Year of publication
1994
Pages
877 - 889
Database
ISI
SICI code
0094-5714(1994)24:6<877:SASOGP>2.0.ZU;2-Z
Abstract
A new Schiff base of picolinaldehyde N-oxide with semicarbazide, [(C7H 8N4O2)2H] (L), and its gold(III), palladium(II) and platinum(IV) compl exes [(L)2H][AuCl] (1), [LH.H2O]2[PdCl4].2H2O (2) and [(L)2H]2[PtCl6]. 6H2O (3) have been synthesized and characterized by elemental analyses , molar conductance, UV, IR, H-1 NMR, fluorescent spectra and TG-DTA t echniques. A single crystal X-ray study of the complex (2) is also rep orted.