The successful development of advanced diesel engines relies heavily o
n piston ring coating materials which can withstand elevated temperatu
res and reduce friction. Traditional hard chrome plating and flame-spr
ayed Mo-wire materials have reached their potential in the diesel engi
ne environment, and alternatives are needed. Thermally-sprayed Mo-base
d alloys and composites are being evaluated for applications as next-g
eneration ring-face coatings. The alloy development task of producing
complex Mo-based alloy powders for use as thermally-sprayed coating ma
terials requires an understanding of their wear resistance under conta
ct stress conditions. In this paper, the wear behavior of Mo and Mo NiCrBSi thermally sprayed coatings is examined by pin-on-disc and sing
le-point scratch-test methods. Microstructural analysis beneath worn r
egions have revealed that fracture of splats and their decohesion cons
titute the mode of failure. Improved wear resistance and stability of
low friction coefficient was obtained by prealloying Mo with NiCrBSi p
rior to thermal spraying.