BIS(TRIFLUOROMETHYLSULFONYLOXY)ORGANOSILI CON COMPOUNDS AS SYNTHETIC MATERIALS FOR NEW SILICON POLYMERS

Authors
UHLIG W
Citation
W. Uhlig, BIS(TRIFLUOROMETHYLSULFONYLOXY)ORGANOSILI CON COMPOUNDS AS SYNTHETIC MATERIALS FOR NEW SILICON POLYMERS, Chemische Berichte, 127(6), 1994, pp. 985-990
Citations number
57
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
6
Year of publication
1994
Pages
985 - 990
Database
ISI
SICI code
0009-2940(1994)127:6<985:BCCASM>2.0.ZU;2-0
Abstract
The new polycarbosilanes, polysiloxanes, and polysilylenealkynes 1c-6c were obtained by condensation of electrophilic omega-bis(trifluoromet hylsulfonyloxy)organosilicon compounds 1b-6b with nucleophiles such as organolithium and organomagnesium compounds. The required silyl trifl ate derivatives 1b-6b have been prepared by reaction of the correspond ing amino-, allyl-, or phenylsilanes 1a-6a with trifluoromethanesulfon ic acid.